6.1 Newtonian viscosity and momentum transport
Viscosity is the resistance a fluid offers to being sheared. It is the first of three classical transport processes — of momentum, heat, and matter — that this chapter shows to share a single mathematical form. This lesson defines viscosity operationally, then explains it microscopically as the diffusion of momentum.
The shear experiment
Confine a fluid between two parallel plates separated by a gap . Hold the lower plate fixed and drag the upper one sideways at velocity . The fluid in contact with each plate moves with it (the no-slip condition), and in steady state the velocity varies linearly across the gap,
To keep the top plate moving, a tangential force per unit area — the shear stress — must be applied. A fluid is Newtonian when that stress is proportional to the velocity gradient it sustains:
The top plate drags the fluid; the bottom plate holds it still. In steady state the velocity is *linear* in y — Couette flow — and the shear stress on either plate is τ = μ ∂u/∂y = μU/h. This is the operational definition of viscosity: the force per unit area required to slide one plate over the other at unit velocity, divided by μ.
The constant of proportionality is the dynamic viscosity , with units of . Water at C has ; air has , some fifty times less. Many common fluids are Newtonian to excellent approximation; polymers, suspensions, and pastes are not, and their nonlinear is the subject of rheology.
Viscosity as a diffusivity of momentum
The shear stress is more than a definition — it is a momentum flux. Each layer of fluid carries -momentum, and the faster layers hand momentum to the slower ones across the planes between them. The stress is exactly the rate at which -momentum is transported per unit area in the -direction. Read this way, says momentum flux is proportional to the gradient of momentum density — the same form a diffusion law takes.
The point is made dimensionally by the kinematic viscosity
which has units of — the units of a diffusion coefficient. Viscosity is the diffusivity of momentum: a velocity disturbance spreads sideways through a fluid exactly as a drop of dye spreads through still water, governed by .
The microscopic origin
For a gas the mechanism is explicit, and follows from the kinetic theory chapter. Molecules in the faster-moving layer thermally wander into the slower layer carrying their surplus momentum, while slower molecules wander the other way; the net momentum exchanged per unit area per unit time is the viscous stress. Estimating the momentum carried across a mean free path by molecules of mean speed gives
This estimate has a striking consequence. The mean speed rises with temperature, , while the product is independent of density (a denser gas has more carriers but a shorter free path, and the two cancel). So gas viscosity rises with temperature and is independent of pressure — both counterintuitive if one pictures viscosity as molecular stickiness, both confirmed by experiment, and both correctly predicted by the momentum-transport picture. Liquids, where molecules are caged by their neighbours rather than flying freely, behave oppositely: their viscosity falls steeply as temperature rises.